Publications

10. Coste, S.C.; Brezny, A.C.; Koronkiewicz, B.K.;  Mayer, J.M. C–H Oxidation in Fluorenyl Benzoates Does Not Proceed Through a Stepwise Pathway: Revisiting Asynchronous Proton-Coupled Electron Transfer. Chem. Sci. 2021, 12, 13127-13136. DOI: 10.1039/d1sc03344a

9. Brezny, A.C.; Nedzbala, H.S.; Mayer, J.M. Multiple Selectivity-Determining Mechanisms of H2O2 Formation in Iron Porphyrin-Catalysed Oxygen Reduction. Chem. Commun. 2021, 57, 1202-1205. denotes co-authors with equal contribution DOI: 10.1039/d0cc06701f

8. Peper, J.L.; Gentry, N.E.; Brezny, A.C.; Field, M.J.; Green, M.T.; Mayer, J.M. Different Kinetic Reactivities of Electrons in Distinct TiO2 Nanoparticle Trap States. J. Phys. Chem. C 2021125, 680-690. DOI: 10.1021/acs.jpcc.0c10633

7. Brezny, A.C.; Johnson, S.I. Raugei, S.; Mayer, J.M. Selectivity-Determining Steps in O2 Reduction Catalyzed by Iron(tetramesitylporphyrin). J. Am. Chem. Soc. 2020, 142, 4108-4113. DOI: 10.1021/jacs.9b13654

6. Pegis, M.L.; Martin, D.J; Wise, C.F.; Brezny, A.C.;  Johnson, S.I.; Johnson, L.E.; Kumar, N.; Raugei, S.; Mayer, J.M. Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin. J. Am. Chem. Soc. 2019141, 8315-8326. DOI: 10.1021/jacs.9b02640

5. Brezny, A.C.; Landis, C.R. Development of a Comprehensive Microkinetic Model for Rh(bis(diazaphospholane))-Catalyzed Hydroformylation. ACS Catalysis 20199, 2501-2513. DOI: 10.1021/acscatal.9b00173

4. Brezny, A.C.; Landis, C.R. Recent Developments in the Scope, Practicality, and Mechanistic Understanding of Enantioselective Hydroformylation. Acc. Chem. Res. 201851, 2344–2354. DOI: 10.1021/acs.accounts.8b00335

3. Wildt, J.; Brezny, A. C.; Landis, C. R. Backbone-Modified Bisdiazaphospholanes for Regioselective Rhodium-Catalyzed Hydroformylation of Alkenes. Organometallics 2017, 36, 3142–3151. DOI: 10.1021/acs.organomet.7b00475

2. Brezny, A.C.; Landis, C.R. Unexpected CO Dependencies, Catalyst Speciation, and Single Turnover Hydrogenolysis Studies of Hydroformylation via High Pressure NMR Spectroscopy. J. Am. Chem. Soc. 2017, 139, 27–2785. DOI: 10.1021/jacs.6b12533

1. Nelsen, E. R.; Brezny, A. C.; Landis, C. R. Interception and Characterization of Catalyst Species in Rhodium Bis(diazaphospholane)-Catalyzed Hydroformylation of Octene, Vinyl Acetate, Allyl Cyanide, and 1-Phenyl-1,3-butadiene. J. Am. Chem. Soc. 2015, 137, 14208–14219. denotes co-authors with equal contribution DOI: 10.1021/jacs.5b09858